Title | Poly-ethyleneterephthalate (PET): Production, quality characteristics, uses, new applications and recycling | |
Authors | Kostas Kotrokois
Laboratory of R&D/Q. Control, Coca-Cola-Frigoglass-V.P.I. S.A., Marousi, Athens, Greece |
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Citation | Kotrokois, K.: Poly-ethyleneterephthalate (PET): Production, quality characteristics, uses, new applications and recycling, Epitheorese Klin. Farmakol. Farmakokinet. 17(1): 43-48 (2003) | |
Publication Date | Received for publication: 15 December 2002
Accepted for publication: 30 January 2003 |
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Full Text Language | English | |
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Keywords | PET, production, quality characteristics, uses, new applications, recycling. | |
Other Terms | review article | |
Summary | Poly ethyleneterephthalate, better known as PET, was patented as a fiber forming polymer in 1941 in England. The intervening 60 year period has seen an ongoing development of the manufacturing technology and engineering to a high degree of sophistication based on the spectacular world-wide growth of PET and diversification of the outlets for it. Besides expanding into a wide range of film outlets, PET applications of bottles (particularly for carbonated soft drinks) and thermoformed containers. The source of PET is crude oil, and the manufacturing of bottle-grade PET resin is based on the polymerization of purified Terephthalic Acid (PTA) and Methyl Ethyl Glycol (MEG) and it is produced through a continuous melt phase and a subsequent solid state polymerization (SSP). PET is a crystalline resin. Final bottle appearance requires that no crystallization occurs in the preforms. An excellent property of PET bottle is low gas permeation. The PET resin quality characteristics are crystallinity, Tg & Tm, density, molecular weight and molecular weight distribution, intrinsic viscosity, viscosity and viscosity in solution, stability, carboxyl end groups concentration, DEG and residual acetaldehyde, cyclic trimers, catalyst residues and color. The Key properties of PET are: molecular weight, Tg and crystallinity. Description of competitive advantages and outstanding properties of oriented PET resin. Elements concerning PET world-wide production, uses, new PET applications and PET recycling. | |
References | 1. Heffelfinger C.J., Knox K.L.: Polyester Films. In: The Science and Technology of Polymer Films. Volume II, Chapter 14, P. 589, Willey-lnterscience, 1971
2. Jabarin S.A., Lofgren E.A.: J. Appl. Polymer Sci, 32: 5315 (1986) 3. Flory P.: Principles of Polymer Chemistry, Chap. III, Cornell Univ. Press, Ithaca, New York, 1953 4. Collins E.A., Bares J., Bilimeyer F.W.,Jr.: Experiments in Polymer Science, John Willey & Sons, Inc., 1973 5. ASTM D 4603-86 Standard Test Method for Determining Inherent Viscosity of PET 6. ASTM D 3418-82 (Reapproved 1988) Standard Test Method for Transition Temperatures of Polymers by Thermal Analysis 7. ASTM D 3417-83 (Reapproved 1988) Standard Test Method for Heats of Fusion and Crystallization of Polymers by Thermal Analysis 8. ASTM D 1505-85 Standard Test Method for Density of Plastics by the Density-Gradient Technique 9. ASTM D 1925-70 (Reapproved 1988) Standard Test Method for Yellowness Index of Plastics 10. Fontaine F., Ledent J., Groeninckx G., Reyanaers H.: Polymer 23: 185 (1982) 11. Billmeyer F.W.,Jr.: Textbook of Polymer Science, 3rd edition, John Willey & Sons, Inc., 1984 12. Fisher G.W., Fakirov S.: J. Matter. Sci. 11:1041 (1976) 13. Bunn C.W., Daubeny R.P.: Proc. R. Soc. A, 226: 531 (1954) 14. Jabarin S.A., Baiduff D.C.: J. Liq. Chromatography 5: 1825-1845 (1982) 15. Patkar M., Jabarin S.A.: Effect of DEG on the Crystallization of PET, ANTEC, 1991 16. Yu Tongyin, Bu Haisan, Chen Jianhua, Mei Jibang, Hu Jialun: Makromol. Chem. 28: 2697 (1986) 17. Zimmermann H., Becker D., Schaff E.: J Appl. Polym. Sei. Appl. Polym. Symp., 35: 183-191 (1979) 18. Zimmermann H., Kim N.T.: Polym. Eng. Sel. 20: 680 (1980) 19. Zimmermann H.: Developments in Polymer Degradation. Applied Science, vol. 5, Chap. 3, London, 1984 20. Giacinand J.R., Miltz J.: In: The Packaging Encyclopedia. Cahners Publishing Co., Boston, MA, pp. 33-38, 1983 21. Crank J.: The Mathematics of Diffusion. Pp. 2-4, Oxford, New York, 1975 22. Steingiser S., et al.: In: Encycl. Chem. Technol. Vol. 3 p. 480, Wiley, N.Y., 1978 23. Greek Codex Alimentarius chapter II article 21 & 26 24. European Community Directive 90/128/EEC 25. Papamargaritis K.: PET: a growing polymer as a packing material. Chemica Chronica: 318-319 (2002) 26. Stewart M.E., Cox A.J., Naylor D.M.: Polymer 34: 4060 (1993) 27. Shepherd F.A., Light R.R.: US Patent 5,006,613 (1991) 28. Hoffman D.C., Caldwell J.K.: Predicting Barrier and Tg Enhancements in PET/PEN Blends. Specialty Polyesters ’95 presentation (1995) 29. Barham V.F.: Hoecht-Celanese close-Loop PET Recycling System. In the 16th International Ryder Conference Proceeding, March 1992 30. Herman L.: Polyester Fibers, Chemistry and Techn., ch.10, Wiley Interscience, 1971 31. Leaversuch R.D.: Chemical Recycling Brings Real Versatility to Solid-waste Management. Modern Plastics, p. 40, July, 1991 |
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